Some Aspects on the Problem of Individual Activity Coefficients of Single-ion Species of Aqueous Strong Electrolytes


  •  Armin Ferse    

Abstract

Individual activity coefficients of single-ion species can neither be defined in thermodynamic terms nor determined experimentally. This does not mean that the individual activity of a single-ion species of an aqueous strong electrolyte does not have a real specifically individual effectiveness. Individual ion activity coefficients are required, for instance, for data about the potentials of single electrodes and liquid junction potentials in galvanic cells with transference. A purely mathematical method is written which allows the factorizing the mean activity coefficient into individual parts of the single-ion species. The experimentally accessible concentration curve of the mean activity coefficient is fitted with a quite new mathematical approach. The parameter set of the mathematical approach can be determined univocally and invariantly with the help of the asymptotic theory using corresponding approximations.



This work is licensed under a Creative Commons Attribution 4.0 License.
  • Issn(Print): 1916-9698
  • Issn(Onlne): 1916-9701
  • Started: 2009
  • Frequency: semiannual

Journal Metrics

Google-based Impact Factor (2018): 10.07

h-index (August 2018): 23

i10-index (August 2018): 76

h5-index (August 2018): 9

h5-median(August 2018): 14

( The data was calculated based on Google Scholar Citations. Click Here to Learn More. )

Contact