Photovoltaic Performance of Spray-Coated Zinc Oxide Nanoparticles Sensitized With Metal-Free Indoline Dyes

Boateng Onwona-Agyeman, Motoi Nakao, Takuya Kitaoka

Abstract


Photovoltaic properties of nano-sized zinc oxide (ZnO) films sensitized with a conventional ruthenium complex (N719) and two metal-free organic indoline dyes (D-149 and D-205) were compared. The ZnO nanoparticles were deposited on transparent conductive aluminum-doped ZnO coated glass substrates (AZO) by spray-coating deposition method and then annealed in air at 500 °C. Using the ZnO-coated AZO as transparent conductive substrates, dye-sensitized solar cells (DSCs) were prepared with the N719, D149 and D205 dyes as the sensitizers. The photoaction spectra of the incident photon-to-current conversion efficiency (IPCE) of the DSCs revealed that the indoline-sensitized solar cells were higher and broader than the ruthenium-sensitized solar cell in the photo-absorption behavior. Under AM 1.5 simulated sunlight (1000 W m-2), the indoline-sensitized ZnO solar cells yielded solar-to-electric energy conversion efficiency of 3.02 and 2.26% for the D-205 and D-149 respectively, while the N719 sensitized ZnO recorded only 0.97%. The superior performance of the indoline-sensitized solar cells was attributed to mainly higher sunlight harvesting efficiency of these metal-free organic dyes.


Full Text: PDF DOI: 10.5539/jmsr.v3n1p87

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution 3.0 License.

Journal of Materials Science Research   ISSN 1927-0585 (Print)   ISSN 1927-0593 (Online)

Copyright © Canadian Center of Science and Education

To make sure that you can receive messages from us, please add the 'ccsenet.org' domain to your e-mail 'safe list'. If you do not receive e-mail in your 'inbox', check your 'bulk mail' or 'junk mail' folders.

------------------------------------------------------------------------------------------------------------------------------

images_120. proquest_logo_120 doaj_logo_new_120