Thermal Adsorption and Catalytic Photodegradation Studies of Carbendazim Fungicide in Natural Soil and Water

Sulaiman G. Muhamad, Kafea M. Shareef, Heman A. Smail

Abstract


Adsorption characteristics and catalytic photodegradation of carbendazim (methyl benzimidazol-2-ylcarbamate) have been investigated in Kurdistan natural soil and different natural waters (drinking, river, lake and ground water). Physico-chemical properties of the natural soil and water were determined. The equilibrium adsorption of carbendazim onto studied soil samples described by Freundlich adsorption model. The catalytic photodegradation processes were studied in aqueous Titanium dioxide (TiO2) suspensions under UV radiation. The kinetic study was done by monitoring the concentration during the degradation process, using High performance Liquid Chromatography (HPLC), coupled with UV-visible spectrophotometer. It was found that the photocatalytic degradation process in this work exhibited pseudo first-order kinetics. The rates of catalytic photodegradation of carbendazim in natural water were lower than that in distilled water.


Full Text: PDF DOI: 10.5539/ijc.v3n2p218

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International Journal of Chemistry   ISSN 1916-9698 (Print)   ISSN 1916-9701 (Online)

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